从超分子聚合物到超分子有机框架:组装溶液相超分子结构的周期性

来自 : www.yxkxyghx.org/CN/abstract/h 发布时间：2021-03-24

Abstract: Formation of periodic networks by molecular building blocks in solution has been a challenge in supramolecular chemistry and self-assembly field. It has been well-established that multitopic building blocks with three or four binding sites can generate supramolecular polymers in solution driven by intermolecular noncovalent interactions. Increasing the rigidity of multitopic building blocks can enhance the preorganization of their binding sites, strengthen the cooperativity and multivalency of intermolecular non-covalent interactions, and increase the ordering or periodicity of their self-assembled architectures. This account summarizes some of the important advance in the construction of supramolecular polymers from multitopic building blocks and our effort in creating two-dimensional (2D) supramolecular organic frameworks (SOFs)-a new family of solution-phase periodic self-assembled networks.
2015年1月1日摘要:单体分子在溶液相自发形成周期性的网络结构,是超分子化学和分子自组装研究领域的重大挑战.多头基分子在溶液相通过分子间非共价键作用可以形成超分子聚合物.提高...超分子框架结构; 超分子聚合物; 自组装; 结构预组织; 芳环堆积; 疏水作用从超分子聚合物到超分子有机框架:组装溶液相超分子结构的周期性